کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5457682 | 1515827 | 2017 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Anomalous packing state in Ce-Ga-Cu bulk metallic glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
Formation mechanism of bulk metallic glasses (BMGs) with high glass-forming ability (GFA) has been a long-standing subject in the field of solid state physics. To highlight the GFA-associated local atomic structure, element-specific positron annihilation spectroscopy was conducted for recently discovered ternary Ce70GaxCu30-x (x = 6-13; at.%) BMGs. We succeeded in identifying the packing structure under the condition of ambient pressure, in which Ce atoms are concentrated more than that in Ce crystal. This anomalous glassy state is most efficiently formed at the Ga concentration of â¼10%, where the best glass-forming ability (GFA) is experimentally observed. First-principles computer simulation results suggest that this anomalous packing structure is associated with Ce-4f electron delocalization in the Ce-Ga-Cu BMGs. The findings provide unambiguous evidence for the relationship between the packing-efficient local structure and the GFA.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Intermetallics - Volume 84, May 2017, Pages 25-29
Journal: Intermetallics - Volume 84, May 2017, Pages 25-29
نویسندگان
Y. Zhao, D.D. Li, B.Y. Qu, R.L. Zhou, B. Zhang, K. Sato,