کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
54762 47025 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Process intensification: New technologies (SMBR and PermSMBR) for the synthesis of acetals
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Process intensification: New technologies (SMBR and PermSMBR) for the synthesis of acetals
چکیده انگلیسی


• SMBR and PermSMBR technologies evaluation for acetals production.
• SMBR leads to high productivities, but also high solvent consumption.
• PermSMBR leads to better performance, but has higher capital and operational costs.

Acetals, as 1,1-diethoxyethane (DEE) and 1,1-dibutoxyethane (DBE), can be used as green oxygenates for diesel blending due to their capacity to reduce particulate matter emissions and to enhance the diesel cetane number. The use of multifunctional technologies, where reaction and separation occur in the same unit, provides the most feasible engineering solution for their synthesis, which involves equilibrium limited reactions. Motivated by that, two innovative technologies for the production of DEE and DBE acetals were explored: the Simulated Moving Bed Reactor and the recently developed Simulated Moving Bed Membrane Reactor – PermSMBR. In this work, the main results and characteristics of each process are presented and discussed.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volumes 218–219, December 2013, Pages 148–152
نویسندگان
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