کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5476571 1521418 2017 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High-temperature oxidation kinetics of iso-octane/n-butanol blends-air mixture
ترجمه فارسی عنوان
سینتیک اکسیداسیون با دمای بالا مخلوط هوا / ایزو اکتان / نان بوتانول
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی (عمومی)
چکیده انگلیسی


- A chemical kinetic model of n-butanol/iso-octane blends (BI) was established.
- Model BI was validated against laminar flame speeds, ignition and JSR data.
- Detailed reaction pathway analysis of n-butanol/iso-octane blends were conducted.
- Key species and reactions for acceleration of laminar flame speed were analyzed.

A chemical kinetic mechanism of n-butanol/iso-octane blends (Model BI) was established on the basis of a n-butanol reaction submechanism and part of a high-temperature oxidation mechanism of iso-octane. Model BI was validated against laminar flame speeds, ignition delay times and JSR data, and proved to be applicable and reliable. It also found that the laminar flame speed of blends increased linearly and monotonically with the increasing ratio of n-butanol. Then detailed kinetic pathway analysis of n-butanol/iso-octane blends were performed based on Model BI to find out the reason for the accelerating effect of added n-butanol. The most influential elementary reactions were determined for the blend, and the laminar flame speed is largely negative related to the concentration of iC4H8, C3H6 and CH3, while C2H4 and C2H3 contribute to the promotion of laminar flame speeds. Flame structures of n-butanol blending with iso-octane were also computed and correspond to the kinetic pathway analysis.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy - Volume 133, 15 August 2017, Pages 443-454
نویسندگان
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