Experimental investigation of changes in petrophysical properties during CO2 injection into dolomite-rich rocks

This experimental study has been carried out to evaluate changes in the petrophysical properties of a number of heterogeneous dolostone samples after undergoing carbonated brine flooding under in-situ reservoir conditions. In this study, the core-flood experiments are complemented by pre- and post-flood porosity, permeability and NMR (nuclear magnetic resonance) measurements, X-ray CT scanning and X-ray Diffraction (XRD) and Energy-Dispersive X-ray (EDX) analysis. Overall, a slight increase in the porosity was observed in most samples, most likely, caused by the dissolution of dolomite (CaMg(CO3)2), calcite (CaCO3) and/or anhydrite (CaSO4). The results also show an increase in the permeability of some samples which again could be attributed to dissolution of the minerals. The X-ray CT images show signs of excessive dissolution of minerals and the creation of dissolution patterns (i.e. wormholes). On the other hand, reductions in permeability and porosity by 57% and 12%, respectively, were also observed in a sample. This is believed to be due to the combined effects of the mineral precipitation and mechanical compaction mechanisms dominating over the mineral dissolution. A small shift in the pore size distribution of the samples towards smaller pore sizes was also observed which is believed to have been caused by mechanical compaction.