کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5499055 | 1533484 | 2017 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fricke-gel dosimeter: overview of Xylenol Orange chemical behavior
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
تشعشع
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The complexation between Xylenol Orange (XO) and Fe3+ ions plays a key role in Fricke-gel dosimeters for the determination of the absorbed dose via UV-vis analysis. In this study, the effect of XO and the acidity of the solution on the complexation mechanism was investigated. Moreover, starting from the results of complexation titration and Equilibrium Restricted Factor Analysis, four XO-Fe3+ complexes were identified to contribute to the absorption spectra. Based on the acquired knowledge, a new [Fe3+] vs dose calibration method is proposed. The preliminary results show a significant improvement of the sensitivity and dose threshold with respect to the commonly used Abs vs dose calibration method.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Radiation Physics and Chemistry - Volume 140, November 2017, Pages 74-77
Journal: Radiation Physics and Chemistry - Volume 140, November 2017, Pages 74-77
نویسندگان
G.M. Liosi, D. Dondi, D.A. Vander Griend, S. Lazzaroni, G. D'Agostino, M. Mariani,