کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5512016 1540217 2017 30 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Epichlorohydrin crosslinked carboxymethyl cellulose-ethylenediamine imprinted polymer for the selective uptake of Cr(VI)
موضوعات مرتبط
علوم زیستی و بیوفناوری بیوشیمی، ژنتیک و زیست شناسی مولکولی زیست شیمی
پیش نمایش صفحه اول مقاله
Epichlorohydrin crosslinked carboxymethyl cellulose-ethylenediamine imprinted polymer for the selective uptake of Cr(VI)
چکیده انگلیسی
A new ion-imprinted polymer (IIP) was synthesized from sodium carboxymethyl cellulose and used for the adsorption of hexavalent chromium from aqueous solution. Epichlorohydrin was used to stabilize the polymer before ethylenediamine (EDA) ligand and Cr(VI) were introduced. The obtained IIP was characterized with FTIR, XPS, TGA,13C NMR, SEM, EDX, BET and zeta sizer. The kinetics of adsorption followed a pseudo-second-order model while the Langmuir adsorption isotherm provided the best fit with a maximum adsorption capacity of 177.62 mg/g at 25 °C. The Langmuir adsorption capacity for the non-imprinted polymer (NIP) at 25 °C was 149.93 mg/g. Thermodynamic parameters indicated an endothermic process and spontaneous adsorption of Cr (VI) on the polymers. IIP adsorbent was successfully recycled 5 times using 0.1 M NaOH as a leachate; 98% Cr(VI) was desorbed during the last adsorption-desorption cycle.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Biological Macromolecules - Volume 101, August 2017, Pages 837-844
نویسندگان
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