Highly selective and stable propane dehydrogenation to propene over dispersed VOx-species under oxygen-free and oxygen-lean conditions

For the first time, we reported on a highly selective propane dehydrogenation to propene over SiO2-supported dispersed VOx species under oxygen-free and oxygen-lean conditions. Propene selectivity above 80% was achieved with propane conversions above 45% at 823–843 K. At operation under oxygen-lean conditions, consecutive propene conversion to COx was significantly suppressed and propene was formed additionally via the highly selective non-oxidative dehydrogenation route over the same catalyst. Usage of SiO2 supports (MCM-41, SBA-15, SiO2) with no strong acid sites and co-feeding of small O2 amounts lead to very limited coke formation (<2 wt. % after 20 h on-stream operation). This results in only slight decrease in time-on-stream performance (ca. 10% of deactivation during 20 h).

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► Highly selective propane dehydrogenation to propene over SiO2-supported dispersed VOx species.
► Propene selectivity above 80% was achieved with propane conversions above 45% at 823–843 K.
► Propane dehydrogenation under oxygen-free and oxygen-lean conditions.
► Propene formation via oxidative and non-oxidative dehydrogenation.
► Usage of SiO2 supports (MCM-41, SBA-15, SiO2) lead to very limited coke formation.
► Only slight decrease in time-on-stream performance during 20 h (ca. 10%).