کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
56896 | 47099 | 2009 | 8 صفحه PDF | دانلود رایگان |
Gold nanoparticles on highly oriented pyrolytic graphite (HOPG) electrodes are synthesized. They are stabilized in nanosized pits of well defined depth in the graphite surface. These pits are created by energetic cluster impact followed by etching under a well controlled oxygen atmosphere. We succeeded in the preparation of highly dispersed and stable Au electrodes with gold particles with a mean diameter smaller than 5 nm. The stability of the gold nanostructures for electrochemical applications has been tested by performing cyclic voltammetric measurements in 0.5 M H2SO4. While conventionally prepared sputter deposited electrodes show highly unstable structures in this size range, Au clusters stabilized in the nanosized containers are stable.
Journal: Catalysis Today - Volume 146, Issues 3–4, 31 August 2009, Pages 378–385