کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
575693 | 1453060 | 2015 | 34 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Degradation of dimethyl sulfoxide through fluidized-bed Fenton process
ترجمه فارسی عنوان
تجزیه دی متیل سولفوکسید از طریق فرایند فنتون فرایند مایع
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
چکیده انگلیسی
Dimethyl sulfoxide (DMSO), one of the most widely used solvent, was subjected to fluidized-bed Fenton oxidation in this study. Fenton oxidation is considered one of the cheapest advanced oxidation processes due to high availability of Fenton's reagents Fe2+ and H2O2, wherein, Fe2+ catalyzes hydroxyl radical production from H2O2. Fluidized-bed Fenton process is a modified approach which is also used to address the production of large amount of iron oxide sludge in conventional Fenton process. Parametric study is included in this research using initial conditions of pH 2-7, 0.5-7.25Â mM Fe2+, 5-87.5Â mM H2O2, and 5-50Â mM DMSO. Fluidized-bed Fenton oxidation of 5Â mM DMSO using 68.97Â g/L SiO2 carrier at initial conditions of pH 3, 5Â mM Fe2+, and 32.5Â mM H2O2 resulted to 95.22% DMSO degradation, 34.38% TOC removal and 0.304Â mM sulfate/mM DMSO0 production in 2Â h. The study shows that the intermediate product which was most difficult to oxidize and contributed most to the residual TOC was methanesulfonate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 300, 30 December 2015, Pages 218-226
Journal: Journal of Hazardous Materials - Volume 300, 30 December 2015, Pages 218-226
نویسندگان
Emmanuela M. Matira, Teng-Chien Chen, Ming-Chun Lu, Maria Lourdes P. Dalida,