Copper smelting and sediment pollution in Bronze Age China: A case study in the Hexi corridor, Northwest China

- Analyzing heavy metal elements in 22 late Neolithic-Bronze Age archaeological sites in Hexi corridor
- Comparing the Cu concentrations in sediment from various lakes near metallurgical center in China
- Revealing the spatial-temporal difference of human smelting activities impact on environment in Bronze Age China
- Providing valuable case study for understanding 'Anthropocene'

The emergence and diffusion of metallurgical technology had tremendous environmental consequence, however, the spatial-temporal consequences of the metallurgy during Bronze Age are not clear in China. In this paper, X-ray fluorescence (XRF) measurement and principal component analysis (PCA) were conducted on heavy metal element (Cu, Ni, Pb, Zn, Cr and As) concentrations (HMEC) of natural and anthropogenic sediment samples systematically collected from 22 late Neolithic-Bronze Age sites in Hexi corridor to explore the potential for subcontinental-wide changes in soil geochemistry. We place this data within the context of the Cu concentrations in lacustrine sediments located near smelting and mining centers in Bronze Age China. Our results show that variation of HMEC in anthropogenic sediment in Hexi corridor is contemporaneous with the increases of the Cu concentrations in lacustrine sediment around 4000 BP. Comparative data suggests the metallurgical production diffused from the Hexi corridor to central and southwestern China around 3600 BP. We argue that sediment pollution is not an isolated phenomenon during the Bronze Age China, but rather occurred on regional scales and is closely related to the intensity of smelting activities.