ArticleA carbon-oxygen-bridged ladder-type building block for efficient donor and acceptor materials used in organic solar cells

A carbon-oxygen-bridged ladder-type donor unit (CO5) was invented and prepared via an “intramolecular demethanolization cyclization” approach. Its single crystal structure indicates enhanced planarity compared with the carbon-bridged analogue indacenodithiophene (IDT). Owing to the stronger electron-donating capability of CO5 than IDT, CO5-based donor and acceptor materials show narrower bandgaps. A donor-acceptor (D-A) copolymer donor (PCO5TPD) and an A-D-A nonfullerene acceptor (CO5IC) demonstrated higher performance than IDT-based counterparts, PIDTTPD and IDTIC, respectively. The better performance of CO5-based materials results from their stronger light-harvesting capability and higher charge-carrier mobilities.