Optimization of the mineralization of a mixture of phenolic pollutants under a ferrioxalate-induced solar photo-Fenton process

The mineralization of solutions containing a mixture of three phenolic compounds, gallic, p-coumaric and protocatechuic acids, in a ferrioxalate-induced solar photo-Fenton process was investigated. The reactions were carried out in a pilot plant consisting of a compound parabolic collector (CPC) solar reactor. An optimization study was performed combining a multivariate experimental design and neuronal networks that included the following variables: pH, temperature, solar power, air flow and initial concentrations of H2O2, Fe(II) and oxalic acid. Under optimal conditions, total elimination of the original compounds and 94% TOC removal of the mixture were achieved in 5 and 194 min, respectively. pH and initial concentrations of H2O2 and Fe(II) were the most significant factors affecting the mixture mineralization. The molar correlation between consumed hydrogen peroxide and removed TOC was always between 1 and 3. A detailed analysis of the reaction was presented. The values of the pseudo-first-order mineralization kinetic rate constant, kTOC, increased as initial Fe(II) and H2O2 concentrations and temperature increased. The optimum pH value also slightly increased with greater Fe(II) and hydrogen peroxide concentrations but decreased when temperature increased. OH and O2− radicals were the main oxidative intermediate species in the process, although singlet oxygen (1O2) also played a role in the mineralization reaction.