کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
580096 1453148 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Adsorption of heavy metals onto activated carbons derived from polyacrylonitrile fiber
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Adsorption of heavy metals onto activated carbons derived from polyacrylonitrile fiber
چکیده انگلیسی
The aim of this research is to produce activated carbons derived from polyacrylonitrile (PAN) fiber and to examine their feasibility of removing heavy metals from aqueous solution. Thermogravimetric analysis was used to identify the suitable conditions for preparing oxidized fiber and coke as activated carbon precursors. Steam and CO2 were used to activate the precursors. Activated carbons were characterized by their pore texture, elemental compositions and surface functionalities. Batch adsorption and desorption studies were carried out to determine the metal-binding ability of activated carbons. Two commercial activated carbon fibers (ACFs), i.e., A-20 and W10-W, were employed to compare the removal performance of PAN derived activated carbons. Influence of oxidation treatment of PAN fiber prior to steam activation was also explored and discussed. Results indicated that steam produced a higher surface area but a lower resultant yield as compared to CO2. Also, precursors activated by steam showed a greater removal performance. For both activation methods, fiber displayed a better metal-binding ability than coke. A small nitrogen loss from PAN fiber as a result of oxidation treatment assisted a greater removal of Cu(II) and Pb(II), but the interaction to Cu(II) was found stronger. It is proposed that the formation of cyclized structure by oxidation treatment minimized the nitrogen loss during steam activation, hence increased the uptake performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 180, Issues 1–3, 15 August 2010, Pages 552-560
نویسندگان
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