کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580152 | 1453144 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Remediation of a hexachlorobenzene-contaminated soil by surfactant-enhanced electrokinetics coupled with microscale Pd/Fe PRB
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Treatment of soils contaminated with chlorinated hydrophobic organic compounds (CHOCs) remains a challenge for environmental scientists worldwide. In this study surfactant-enhanced electrokinetics (SEEK) was coupled with permeable reactive barrier (PRB) composed of microscale Pd/Fe to treat a hexachlorobenzene (HCB)-contaminated soil. A nonionic surfactant, Triton X-100 (TX-100), was selected as the solubility-enhancing agent. Five bench-scale tests were conducted to investigate the performance of EK-PRB on HCB removal from soils. Results showed that the HCB removal was generally increased by a factor of 4 by EK coupled with PRB compared with EK alone (60% versus 13%). In the EK-PRB system, HCB was removed from soil through several sequential processes: the movement driven by electroosmotic flow (EOF) in the anode column, the complete adsorption/degradation by the reactive Pd/Fe particles in PRB, and the consequent movement by EOF and probable electrochemical reactions in the cathode column. TX-100 was supposed to be a superior enhancement agent for HCB removal, not only in the EOF movement process but also in the Pd/Fe degradation process. This study indicates that the combination of SEEK and Pd/Fe PRB is efficient and promising to remove CHOCs from contaminated soils.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 184, Issues 1â3, 15 December 2010, Pages 184-190
Journal: Journal of Hazardous Materials - Volume 184, Issues 1â3, 15 December 2010, Pages 184-190
نویسندگان
Jinzhong Wan, Zhirong Li, Xiaohua Lu, Songhu Yuan,