کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580739 | 1453156 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reductive dechlorination of carbon tetrachloride in acidic soil manipulated with iron(II) and bisulfide ion
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reductive dechlorination of carbon tetrachloride in acidic soil manipulated with iron(II) and bisulfide ion Reductive dechlorination of carbon tetrachloride in acidic soil manipulated with iron(II) and bisulfide ion](/preview/png/580739.png)
چکیده انگلیسی
Batch and column tests were conducted to investigate the effect of reductant concentration, reductant contact time, and suspension pH on reductive dechlorination of carbon tetrachloride (CT) by soil manipulated with Fe(II) and HSâ. Kinetic rate constants for the reductive dechlorination increased as the reductant concentrations increased. Fe(II) was more effective reductant than HSâ, resulting in higher rate constants. The contact time of 1 day for the soil with HSâ and that of 4Â h with Fe(II) showed the highest reaction rates, respectively. The kinetic rate constants increased as the pH of soil suspensions with Fe(II) (5.2-8.0) and HSâ (8.3-10.3) increased. Soil column with Fe(II) showed larger bed volumes (13.8) to reach a column breakthrough than that with HSâ (4.0). Fe(II) treatment showed better removal of CT in the soil column with the addition of CaO than HSâ treatment did. In contrast, HSâ treatment not producing toxic products could be considered as an environmentally favorable reductant.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 172, Issues 2â3, 30 December 2009, Pages 623-630
Journal: Journal of Hazardous Materials - Volume 172, Issues 2â3, 30 December 2009, Pages 623-630
نویسندگان
Kyunghoon Choi, Woojin Lee,