کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
58086 | 47141 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reaction pathways and kinetics of the gas-phase oxidation of cyclohexane on NiO/γ-Al2O3 catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A NiO/γ-Al2O3 catalyst with a nearly monolayer dispersion of active nickel oxide species on the carrier was synthesized and investigated for the selective oxidehydrogenation of cyclohexane to cyclohexene. Integral measurements were performed to determine the reaction network and products distribution and differential measurements for kinetic investigations. The kinetic study showed a mechanism change in the temperature range of 573–603 K. From 513 to 573 K the oxidation took place via electrophilic oxygen species and from 603 to 723 K with nucleophilic oxygen species. The reaction order of cyclohexane is 1.0 in the lower temperature range and 0.5 in the higher one.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 117, Issues 1–3, 30 September 2006, Pages 253–258
Journal: Catalysis Today - Volume 117, Issues 1–3, 30 September 2006, Pages 253–258
نویسندگان
F. Patcas, F.C. Patcas,