کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
581957 877849 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preconcentration and determination of trace metal ions from aqueous samples by newly developed gallic acid modified Amberlite XAD-16 chelating resin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Preconcentration and determination of trace metal ions from aqueous samples by newly developed gallic acid modified Amberlite XAD-16 chelating resin
چکیده انگلیسی
Gallic acid was immobilized on Amberlite XAD-16 by coupling it through -NN group. The resulting chelating resin AmberliteXAD-16 gallic acid, characterized by thermogravimetric analysis (TGA), infrared (IR) spectra and BET analysis, was used to preconcentrate Cr(III), Mn(II),Fe(III),Co(II), Ni(II) and Cu(II)ions. The resin was employed for the preconcentration of the metal ions present in river water and industrial area aqueous samples. Several parameters like effect of pH, effect of time, effect of sample volume and flow rate of sample were investigated. The sorption capacities for the resin were 216 μmol g−1, 180 μmol g−1, 403 μmol g−1, 281 μmol g−1, 250 μmol g−1 and 344 μmol g−1 for Cr(III), Mn(II), Fe(III), Co(II), Ni(II) and Cu(II) respectively. The preconcentration factors for Cr(III), Mn(II),Fe(III),Ni(II),Co(II) and Cu(II) were found out to be 300, 200, 400, 285.7, 300 and 400 respectively. The effect of various interfering ions was also studied. Results were validated by using standard addition method for river water sample.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 163, Issue 1, 15 April 2009, Pages 295-301
نویسندگان
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