کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
582675 | 1453167 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Application of immobilized nanotubular TiO2 electrode for photocatalytic hydrogen evolution: Reduction of hexavalent chromium (Cr(VI)) in water
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
In this study, immobilized TiO2 electrode is applied to reduce toxic Cr(VI) to non-toxic Cr(III) in aqueous solution under UV irradiation. To overcome the limitation of powder TiO2, a novel technique of immobilization based on anodization was applied and investigated under various experimental conditions. The anodization was performed at 20 V-5 °C for 45 min with 0.5% hydrofluoric acid, and then the anodized samples were annealed under oxygen stream in the range 450-850 °C. Based on the results of the experiments, the photocatalytic Cr(VI) reduction was favorable in acidic conditions, with â¼98% of the Cr(VI) being reduced within 2 h at pH 3. Among the samples tested under same anodizing condition, the nanotubular TiO2 annealed at 450 and 550 °C showed highest reduction efficiencies of Cr(VI). In addition, the surface characterizations (zeta potential, XRD, and SEM) of these samples proved that the Cr(VI) reduction efficiency was higher under acidic conditions and at a lower annealing temperature. From this research, it was concluded that the anodized TiO2 has the potential to be a useful technology for environmental remediation as well as photocatalytic hydrogen production from water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 161, Issues 2â3, 30 January 2009, Pages 1069-1074
Journal: Journal of Hazardous Materials - Volume 161, Issues 2â3, 30 January 2009, Pages 1069-1074
نویسندگان
Jaekyung Yoon, Eunjung Shim, Sanghyun Bae, Hyunku Joo,