کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
582722 | 1453168 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The removal of an anionic red dye from aqueous solutions using chitosan beads-The role of experimental factors on adsorption using a full factorial design
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
A factorial design was employed to evaluate the quantitative removal of an anionic red dye from aqueous solutions on epichlorohydrin-cross-linked chitosan. The experimental factors and their respective levels studied were the initial dye concentration in solution (25 or 600 mg Lâ1), the absence or the presence of the anionic surfactant sodium dodecylbenzenesulfonate (DBS) and the adsorption temperature (25 or 55 °C). The adsorption parameters were analyzed statistically using modeling polynomial equations. The results indicated that increasing the dye concentration from 25 to 600 mg Lâ1 increases the dye adsorption whereas the presence of DBS increases it. The principal effect of temperature did not show a high statistical significance. The factorial results also demonstrate the existence of statistically significant binary interactions of the experimental factors. The adsorption thermodynamic parameters, namely ÎadsH, ÎadsG and ÎadsS, were determined for all the factorial design results. Exothermic and endothermic values were found in relation to the ÎadsH. The positive ÎadsS values indicate that entropy is a driving force for adsorption. The ÎadsG values are significantly affected by an important synergistic effect of the factors and not by the temperature changes alone.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 160, Issues 2â3, 30 December 2008, Pages 337-343
Journal: Journal of Hazardous Materials - Volume 160, Issues 2â3, 30 December 2008, Pages 337-343
نویسندگان
Antonio R. Cestari, Eunice F.S. Vieira, Jackeline A. Mota,