کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
582784 | 877859 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, structural investigation, thermal decomposition mechanism and sensitivity properties of an energetic compound [Cd(DAT)6](ClO4)2 (DATÂ =Â 1,5-diaminotetrazole)
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
An energetic coordination compound [Cd(DAT)6](ClO4)2 has been synthesized by using 1,5-diaminotetrazole (DAT) as ligand and its structure has been characterized by applying X-ray single crystal diffraction, elemental analysis and FT-IR spectroscopy. The central cadmium(II) cation is coordinated by six N atoms from six DAT molecules to form a six-coordinated and distorted octahedral structure. Di-dimension layer structure was formed and the layers were linked together by the extensive intermolecular hydrogen bonds between DAT ligands and ClO4â anions. Thermal decomposition mechanism of the title compound was predicted based on DSC, TG-DTG and FT-IR analyses results. The kinetic parameters of the first exothermic process of the title compound were studied by applying the Kissinger's and Ozawa-Doyle's methods. Sensitivity tests reveal that the title compound has sensitive nature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 160, Issue 1, 15 December 2008, Pages 45-50
Journal: Journal of Hazardous Materials - Volume 160, Issue 1, 15 December 2008, Pages 45-50
نویسندگان
Yan Cui, Jianguo Zhang, Tonglai Zhang, Li Yang, Jin Zhang, Xiaochun Hu,