کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
582990 | 1453169 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Extractive removal of chromium (VI) from industrial waste solution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Extractive removal of Cr (VI) was carried out from chloride solutions using cyanex 923 mixed with kerosene. The efficiency of this extractant was studied under various experimental conditions, such as concentration of different mineral acids in the aqueous phase, concentration of cyanex 923 and Cr (VI) present in the initial aqueous feed, temperature and time of extraction, organic to aqueous (O/A) phase ratio. Percentage Cr (VI) extraction decreases with the increase in temperature at varying concentration of cyanex 923. The interference of the impurities usually associated with Cr (VI) such as Cr (III), Cu, Ni, Fe (II), Zn, Chloride and sulphate, etc., were examined under the optimized conditions and only Zn was found to interfere. Under the optimum experimental conditions 98.6-99.9% of Cr (VI) was extracted in 3-5Â min at O/A of 2 with the initial feed concentration of 1Â g/L of Cr (VI). The extracted Cr (VI) was quantitatively stripped with 1Â M NaOH and the organic phase obtained after the stripping of Cr (VI) was washed with dilute HCl solution to neutralize any NaOH trapped/adhered to the solvent and then with distilled water. This regenerated solvent was reused in succeeding extraction of chromium (VI). Finally a few experiments were performed with the synthetic effluent from an electroplating industry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 159, Issues 2â3, 30 November 2008, Pages 458-464
Journal: Journal of Hazardous Materials - Volume 159, Issues 2â3, 30 November 2008, Pages 458-464
نویسندگان
Archana Agrawal, Chandana Pal, K.K. Sahu,