Ni(II) removal from aqueous effluents by silylated clays

Industrial effluents discharged in water bodies without proper treatment contribute to water pollution by potentially toxic metal ions. Considering that the legislation for discarding of such effluents is getting more and more rigorous, the development of efficient processes for the treatment of industrial effluents is of great interest. A study on the capacity of metal retention by silylated-modified clays was carried out with the aim to evaluate the efficiency of this application. K10 clay was modified with 3-mercaptopropyltrimethoxysilane (MPS) and tested in batch removal processes. We investigated the sorption process, obtaining isotherms and kinetics of adsorption and the influence of pH, the desorption process and the metal recovery. It was observed that the modified clay presents fast retention and good capacity of both adsorption and desorption. The use of K10/MPS as adsorbent shows to be more adequate in effluent final polishment, after a conventional treatment, or when Ni(II) initial concentration in the effluent is low enough to permit its adequate removal by conventional methods.