کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
583376 | 877870 | 2008 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Application of chitosan as flocculant for coprecipitation of Mn(II) and suspended solids from dual-alkali FGD regenerating process
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Heavy metals and suspended solid (SS) needed to be removed from the recirculation of dual-alkali flue gas desulfurization (FGD) system. The feasibility of coprecipitation of heavy metal and SS by water-soluble chitosan was studied in a lab scale experiment. The association between chitosan and metal ions was verified through DSC and FT-IR. The pH investigation revealed that at the pH ranged from 5 to 9, there were three stages for different actions: adsorption of chitosan for Mn(II), precipitation of manganese hydroxide and coprecipitation of manganese hydroxide and chitosan-Mn(II) complex. The ion selectivity experiments showed that the occurrence of Ca(II) in the solution had little influence on the adsorption of chitosan for Mn(II). The decrease rate of adsorption capacity was about 0.0023 mmol gâ1 per 1 mg Lâ1 Ca(II). When adsorption and flocculation of chitosan occurred at the same time and at the sufficient addition of chitosan, chitosan not only made solids flocculate but also enhanced sorption capacity of chitosan. Application of chitosan for coprecipitation of Mn(II) and SS could remove Mn(II) efficiently and improve the settling characteristics of SS from dual-alkali FGD regenerating process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 152, Issue 2, 1 April 2008, Pages 757-764
Journal: Journal of Hazardous Materials - Volume 152, Issue 2, 1 April 2008, Pages 757-764
نویسندگان
Zhong-Biao Wu, Wei-Min Ni, Bao-Hong Guan,