کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
583623 | 1453174 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
EDTA impact on Cd2+ migration in apatite-water system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
The impact factors on Cd sorption and desorption in aqueous solution on apatite were studied. Batch experiments were carried out using synthetic hydroxyapatite with Ca/P 1.44, 1.66 and 1.94 in Cd(NO3)2 and Cd(NO3)2-EDTA equimolar complex solutions in the pH range from 4 to 7. It was established that Cd sorption on apatite depends not only on apatite specific surface area but also on Ca/P mole ratio in apatite as well as on the presence of chelating compounds. Presence of EDTA in the solution decreases the amount of Cd bound. [CdEDTA]2â prevents chemical sorption of Cd2+ ions on apatite. EDTA considerably decreases the sorption capacity of apatite with Ca excess. Impact of EDTA is smaller for the stoichiometric apatite and for the apatite with calcium deficiency. Cd bound due to adsorption is more easily removed from apatite. Ca2+ ions increase and presence of EDTA in a solution cause total Cd desorption from apatite.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 154, Issues 1â3, 15 June 2008, Pages 491-497
Journal: Journal of Hazardous Materials - Volume 154, Issues 1â3, 15 June 2008, Pages 491-497
نویسندگان
Kaia Tõnsuaadu, Karin Viipsi, Andres Trikkel,