کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
583751 | 877876 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Occurrence of priority organic pollutants in the fertilizers, China
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
The use of large quantities of chemical fertilizers is usually associated with environmental problems. A lot of work has been done on the concentrations of heavy metals and radionuclides in chemical fertilizers, but little work has focused on the occurrence of semi-volatile organic compounds (SVOCs). In this study the occurrence of 43 SVOCs listed as priority pollutants in 22 widely used-fertilizers of China was determined by gas chromatography coupled with mass spectrometry. Twenty-six SVOCs were detected with different detection frequencies and concentrations. The most abundant compounds were phthalic acid esters (PAEs; ranging from 1.17 to 2795 μg kgâ1 dry weight, d.w.) and nitroaromatics (up to 9765 μg kgâ1 d.w.), followed by polycyclic aromatic hydrocarbons (PAHs; <140 μg kgâ1 d.w.) and halogenated hydrocarbons (<900 μg kgâ1 d.w.). Chlorobenzenes and haloethers occurred generally at low concentrations. There are large variations in concentrations of various compounds in different fertilizers, and the total concentrations of each class of contaminants varied widely, too. The highest levels of sum concentration for 16 PAHs, for 6 PAEs and for nitroaromatics were found in organic fertilizer containing pesticide and soil amendments. Concentrations of SVOCs in coated fertilizers (the controlled release fertilizer with coating) were considerably higher than those in the corresponding fertilizers without coating. The occurrence frequencies of SVOCs in the straight fertilizers (containing only one of the major plant nutrients) were lower than in the other fertilizers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 152, Issue 3, 15 April 2008, Pages 1208-1213
Journal: Journal of Hazardous Materials - Volume 152, Issue 3, 15 April 2008, Pages 1208-1213
نویسندگان
Ce-Hui Mo, Quan-Ying Cai, Yun-Hui Li, Qiao-Yun Zeng,