کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
584260 | 1453181 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of xylenol orange functionalized silica gel as a selective solid phase extractor and its application for preconcentration-separation of mercury from waters
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Preparation of xylenol orange functionalized silica gel as a selective solid phase extractor and its application for preconcentration-separation of mercury from waters Preparation of xylenol orange functionalized silica gel as a selective solid phase extractor and its application for preconcentration-separation of mercury from waters](/preview/png/584260.png)
چکیده انگلیسی
A new selective solid phase extractor was prepared from silica gel modified with xylenol orange (SGMXO). The solid phase extractor is stable in 6 mol Lâ1 HCl, common organic solvents, and pH 1.0-9.0 buffer solutions. In the batch experiments, Hg(II) can be adsorbed on SGMXO at pH 1.0 with 90.0% retention, whereas the retention of other common coexisting metal ions such as Cd(II), Pb(II), Cu(II), Ni(II), Co(II), Mn(II), Zn(II), and Fe(III) is less than 4.1%.. The adsorption equilibration for Hg(II) was achieved within 3 min. At optimum conditions, the adsorption capacity of the extractor is 18.26 μmol gâ1 of dry modified silica gel, and the preconcentration factor is as high as 333. The recovery is still higher than 95% for the preconcentration of 10 ng mLâ1 Hg(II). The new solid phase extractor has been used for the preconcentration of low level of Hg(II) in surface water, tap water in chemistry laboratory and student's dormitory and a simulated sea water samples, recoveries of 98.2-100.6% were obtained. It is showed that low level of Hg(II) can be effectively preconcentrated by this new selective solid phase extractor.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 145, Issues 1â2, 25 June 2007, Pages 323-330
Journal: Journal of Hazardous Materials - Volume 145, Issues 1â2, 25 June 2007, Pages 323-330
نویسندگان
Jing Fan, Chunlai Wu, Yafang Wei, Chuanyun Peng, Pingan Peng,