کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
584522 | 1453184 | 2007 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Removal of basic yellow dye from aqueous solution by sorption on green alga Caulerpa scalpelliformis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Dynamic batch experiments were carried out for the biosorption of basic yellow dye on to the green macroalgae Caulerpa scalpelliformis. The factors affecting the sorption process such as the initial concentration of the dye and pH of the solution, the adsorbent dosage and the time of contact were studied. The sorption kinetics followed pseudo-second order kinetic model. The Caulerpa species exhibited a maximum uptake of 27 mg of dye per gram of seaweed. The Boyd's plot confirmed the external mass transfer as the rate-limiting step. The average effective diffusion coefficient was found to be 2.47 Ã 10â4 cm2/s. Sorption equilibrium studies demonstrated that the biosorption followed Freundlich isotherm model, which implies a heterogeneous sorption phenomenon. Various thermodynamic parameters such as enthalpy of sorption ÎH°, free energy change ÎG° and entropy ÎS° were estimated. The negative value of ÎH° and negative values of ÎG° show the sorption process is exothermic and spontaneous. The negative value of entropy ÎS° shows the decreased randomness at the solid-liquid interface during the sorption of dyes onto green seaweed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 142, Issues 1â2, 2 April 2007, Pages 68-76
Journal: Journal of Hazardous Materials - Volume 142, Issues 1â2, 2 April 2007, Pages 68-76
نویسندگان
Rathinam Aravindhan, Jonnalagadda Raghava Rao, Balachandran Unni Nair,