کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
584522 1453184 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Removal of basic yellow dye from aqueous solution by sorption on green alga Caulerpa scalpelliformis
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Removal of basic yellow dye from aqueous solution by sorption on green alga Caulerpa scalpelliformis
چکیده انگلیسی
Dynamic batch experiments were carried out for the biosorption of basic yellow dye on to the green macroalgae Caulerpa scalpelliformis. The factors affecting the sorption process such as the initial concentration of the dye and pH of the solution, the adsorbent dosage and the time of contact were studied. The sorption kinetics followed pseudo-second order kinetic model. The Caulerpa species exhibited a maximum uptake of 27 mg of dye per gram of seaweed. The Boyd's plot confirmed the external mass transfer as the rate-limiting step. The average effective diffusion coefficient was found to be 2.47 × 10−4 cm2/s. Sorption equilibrium studies demonstrated that the biosorption followed Freundlich isotherm model, which implies a heterogeneous sorption phenomenon. Various thermodynamic parameters such as enthalpy of sorption ΔH°, free energy change ΔG° and entropy ΔS° were estimated. The negative value of ΔH° and negative values of ΔG° show the sorption process is exothermic and spontaneous. The negative value of entropy ΔS° shows the decreased randomness at the solid-liquid interface during the sorption of dyes onto green seaweed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 142, Issues 1–2, 2 April 2007, Pages 68-76
نویسندگان
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