کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
585893 | 1453193 | 2006 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of acid-catalyzed cleavage of cumene hydroperoxide
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Kinetics of acid-catalyzed cleavage of cumene hydroperoxide Kinetics of acid-catalyzed cleavage of cumene hydroperoxide](/preview/png/585893.png)
چکیده انگلیسی
The cleavage of cumene hydroperoxide, in the presence of sulfuric acid, to form phenol and acetone has been examined by adiabatic calorimetry. As expected, acid can catalyze cumene hydroperoxide reaction at temperatures below that of thermally-induced decomposition. At elevated acid concentrations, reactivity is also observed at or below room temperature. The exhibited reactivity behavior is complex and is significantly affected by the presence of other species (including the products). Several reaction models have been explored to explain the behavior and these are discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 130, Issues 1–2, 17 March 2006, Pages 88–106
Journal: Journal of Hazardous Materials - Volume 130, Issues 1–2, 17 March 2006, Pages 88–106
نویسندگان
M.E. Levin, N.O. Gonzales, L.W. Zimmerman, J. Yang,