Selective oxidation of alcohols over nickel zirconium phosphate

Nickel zirconium phosphate nanoparticles were found to function as efficient catalysts for the selective oxidation of a wide range of alcohols to their corresponding ketones and aldehydes using H2O2 as an oxidizing agent and without any organic solvents, phase transfer catalysts, or additives. The steric and electronic properties of various substrates had significant influence on the reaction conditions required to achieve acetylation. The results showed that this method can be applied for the chemoselective oxidation of benzyl alcohols in the presence of aliphatic alcohols. The catalyst used in the current study was characterized by ICP-OES, XRD, NH3-TPD, Py-FTIR, N2 adsorption-desorption, SEM and TEM. These analyses revealed that the interlayer distance in the catalyst increased from 0.75 to 0.98 nm when Ni2+ was intercalated between the layers, whereas the crystallinity of the material was reduced. The nanocatalyst could also be recovered and reused at least seven times without any discernible decrease in its catalytic activity. This new method for the oxidation of alcohols has several key advantages, including mild and environmentally friendly reaction conditions, short reaction time, excellent yields and a facile work-up.

Graphical AbstractNickel zirconium phosphate was prepared and used as an efficient catalyst for the selective oxidation of various alcohols to the corresponding aldehydes and ketones, in good yields and with excellent selectivity.Figure optionsDownload as PowerPoint slide