کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
59069 | 1419452 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
As compared to conventional micrometer-sized mordenite particles, nanometer-sized mordenite gave a much higher activity and better stability in dimethyl ether carbonylation to methyl acetate by suppressing the deposition of hard coke. A structural analysis revealed that intra-crystalline diffusion limitation of the reactants and products to and from the active sites inside the channels was greatly decreased by reducing the zeolite size to the nanometer size.
Graphical AbstractNanometer-sized H-mordenite (HMOR) showed a much higher reaction rate and stability than micrometer-sized HMOR, resulting from the improvement of molecule transportation efficiency by reducing the crystalline size.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 34, Issue 8, August 2013, Pages 1496–1503
Journal: Chinese Journal of Catalysis - Volume 34, Issue 8, August 2013, Pages 1496–1503
نویسندگان
Huifu Xue, Xiumin Huang, Evert Ditzel, Ensheng Zhan, Meng Ma, Wenjie Shen,