کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
59087 | 1419436 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The use of a thermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100% and 98%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.
Graphical AbstractAn active selective and recyclable thermoregulated phase-transfer rhodium nanoparticle catalyst was applied to the hydrogenation of ortho-chloronitrobenzene to ortho-chloroaniline.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 35, Issue 12, December 2014, Pages 1917–1920
Journal: Chinese Journal of Catalysis - Volume 35, Issue 12, December 2014, Pages 1917–1920
نویسندگان
Zhijun Chen, Yanhua Wang, Wenjiang Li, Jingyang Jiang, Zilin Jin,