کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
59087 1419436 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene
چکیده انگلیسی

The use of a thermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100% and 98%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.

Graphical AbstractAn active selective and recyclable thermoregulated phase-transfer rhodium nanoparticle catalyst was applied to the hydrogenation of ortho-chloronitrobenzene to ortho-chloroaniline.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 35, Issue 12, December 2014, Pages 1917–1920
نویسندگان
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