کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
602259 | 879969 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of Zr(IV) entrapped chitosan polymeric matrix for selective fluoride sorption
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
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چکیده انگلیسی
The Zr(IV) loaded carboxylated chitosan beads (Zr-CCB) was synthesised and fluoride removal studies were carried out in batch equilibration method. The results shows an enhanced defluoridation capacity (DC) of Zr-CCB (4850 mg Fâ/kg) than the carboxylated chitosan beads (CCB) and raw chitosan beads (CB) which possesses the DCs of 1385 and 52 mg Fâ/kg, respectively. The mechanism of fluoride removal by Zr-CCB is governed by both adsorption and complexation. The presence of functional groups, elements and the surface morphology of the sorbent were confirmed by FTIR and SEM with EDAX analysis. The experimental data have been analysed using Freundlich, Langmuir and Dubinin-Radushkevich (D-R) isotherms. The best fit isotherm model was identified using various methods of non-linear analysis. Thermodynamic parameters such as ÎG°, ÎH° and ÎS° were calculated to predict the nature of fluoride sorption. A field trial was carried out with fluoride water collected from a nearby fluoride-endemic village.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces B: Biointerfaces - Volume 72, Issue 1, 1 August 2009, Pages 88-93
Journal: Colloids and Surfaces B: Biointerfaces - Volume 72, Issue 1, 1 August 2009, Pages 88-93
نویسندگان
Natrayasamy Viswanathan, S. Meenakshi,