Silver nanoparticles embedded over porous metal organic frameworks for carbon dioxide fixation via carboxylation of terminal alkynes at ambient pressure

Ag nanoparticles has been supported over a porous Co(II)-salicylate metal-organic framework material and resulting AgNPs@CO-MOF showed excellent catalytic efficiency in the carboxylation of terminal alkynes via CO2 fixation reaction to yield alkynyl carboxylic acids under mild reaction conditions.176