Adsorption of phenols from aqueous solutions: Equilibria, calorimetry and kinetics of adsorption

The brief theoretical description of the phenols adsorption from aqueous solutions on carbonaceous adsorbents, i.e. activated carbons (ACs) and activated carbon fibers (ACFs) has been presented. The description includes adsorption equilibria, calorimetry as well as kinetics of adsorption. The generalized Langmuir–Freundlich (GLF) isotherm equation has been used to study of the cooperative effect of the surface heterogeneity and the lateral interactions between the admolecules. Theoretical isosteric heats of adsorption connected with the GLF model have been estimated too. Knowledge of both adsorption equilibria and heats of adsorption is fundamental for adequate description of any adsorption process. To correlate the kinetic data of the studied systems, the theoretical equations developed from Statistical Rate Theory (SRT) of Interfacial Transport were applied. The most advantageous of the proposed model of calculations is the set of common parameters appearing in each type of expressions, which significantly extends the possibility of their interpretation. Theoretical studies were fully reviewed using the literature experimental adsorption data. They included the data of phenols adsorption both on ACs and ACFs surfaces.

The generalized Langmuir–Freundlich (GLF) isotherm equation has been applied to study the cooperative effect of the surface heterogeneity and the lateral interactions between the adjacent molecules.Figure optionsDownload high-quality image (80 K)Download as PowerPoint slideResearch highlights
► Energetic heterogeneity plays a more essential role than lateral interaction effects.
► Utility of the SRT model for the description of adsorp. kinetics has been confirmed.
► Set of common parameters in each type of theoret. eqs (consistency of approach).