کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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61744 | 47603 | 2011 | 9 صفحه PDF | دانلود رایگان |

Decamethylosmocene, (Me5C5)2Os (1), is a pre-catalyst in a very efficient oxidation of alkanes with hydrogen peroxide in acetonitrile at 20–60 °C. The reaction proceeds with a substantial lag period that can be reduced by the addition of pyridine in a small concentration. The lag period can be removed if 1 is incubated with pyridine and/or H2O2 in MeCN prior to the alkane oxidation. Alkanes, RH, are oxidized primarily to the corresponding alkyl hydroperoxides, ROOH. Turnover numbers attain 51,000 in the case of cyclohexane (maximum turnover frequency was 6000 h−1) and 3600 in the case of ethane. The oxidation of benzene and styrene also occurs with a lag period to afford phenol and benzaldehyde, respectively. A kinetic study of cyclohexane oxidation and selectivity parameters (measured in the oxidation of n-heptane, methylcyclohexane, isooctane, cis- and trans-dimethylcyclohexanes) indicates that the oxidation of saturated, olefinic, and aromatic hydrocarbons proceeds with the participation of hydroxyl radicals. The 1/H2O2/py/MeCN system also oxidizes 1-phenylethanol to acetophenone.
Decamethylosmocene, (Me5C5)2Os (1), is a pre-catalyst in a very efficient oxidation of alkanes with hydrogen peroxide in acetonitrile at 20–60 °C. Turnover numbers attain 51,000 in the case of cyclohexane (maximum turnover frequency was 6000 h−1) and 3600 in the case of ethane.Figure optionsDownload high-quality image (67 K)Download as PowerPoint slideResearch highlights
► Decamethylosmocene, (Me5C5)2Os (1), very efficiently catalyzes the oxidation of alkanes with hydrogen peroxide in acetonitrile at 20–60 °C.
► A kinetic study of cyclohexane oxidation and selectivity parameters indicate that the oxidation of saturated, olefinic and aromatic hydrocarbons proceeds with the participation of hydroxyl radicals.
► Alcohols are oxidized by this system to the corresponding ketones.
Journal: Journal of Catalysis - Volume 277, Issue 2, 24 January 2011, Pages 164–172