کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
61857 47609 2010 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Assembly of cyclic hydrocarbons from ethene and propene in acid zeolite catalysis to produce active catalytic sites for MTO conversion
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Assembly of cyclic hydrocarbons from ethene and propene in acid zeolite catalysis to produce active catalytic sites for MTO conversion
چکیده انگلیسی

The formation of cyclic hydrocarbons from smaller building blocks such as ethene and propene is investigated in protonated ZSM-5, using a 2-layered ONIOM(B3LYP/6-31+g(d):HF/6-31+g(d)) approach and an additional Grimme-type van der Waals dispersion correction term to account for the long-range dispersion interactions. These cyclic species form precursors for active hydrocarbon pool species and play a key role in activating the acidic zeolite host for successful methanol-to-olefin (MTO) conversion. Starting from trace amounts of ethene and propene that are formed during an initial induction period or during the active phase, dimerization reactions allow for rapid chain growth. The products of these reactions can be neutral alkenes, framework-bound alkoxide species or intermediate carbenium ions, depending on the zeolite environment taken into account. On the basis of rate constants for successive reaction steps, a viable route toward cyclization is proposed, which starts from the formation of a framework-bound propoxide from propene, followed by dimerization with an additional propene molecule to form the 2-hexyl carbenium ion which finally undergoes ring closure to yield methylcyclopentane. This cyclic species in turn forms a precursor for either an active hydrocarbon pool compound or for deactivating coke deposit.

The formation of cyclic hydrocarbons from basic ethene and propene building blocks was investigated in protonated ZSM-5 using a 2-layered ONIOM(B3LYP/6-31+g(d):HF/6-31+g(d)) method including van der Waals corrections. A low-energy pathway starting from propene was found that eventually formed the methylcyclopentane species via intermediate stepwise dimerization.Figure optionsDownload high-quality image (85 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 271, Issue 1, 12 April 2010, Pages 67–78
نویسندگان
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