کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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62042 | 47618 | 2009 | 4 صفحه PDF | دانلود رایگان |
In-situ13C MAS NMR techniques were used to investigate the effects of different solvent systems on the formation of phenylacetaldehyde (PADH) over TS-1 zeolite. Protic solvents such as water and methanol provide acidic centers during the reaction. These acidic species catalyzed the transformation of the intermediates to PADH. Whereas in the presence of aprotic solvents such as acetone, the precursor of PADH remains stable on the framework of TS-1 and accordingly there is no PADH formation.
In-situ13C MAS NMR experiments presented that protic solvents such as water and methanol provide acidic centers during the reaction, which is a unique factor to form phenylacetaldehyde over TS-1 zeolite.Figure optionsDownload high-quality image (27 K)Download as PowerPoint slide
Journal: Journal of Catalysis - Volume 267, Issue 2, 25 October 2009, Pages 177–180