کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
621358 882549 2012 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Production of microporous palm shell based activated carbon for methane adsorption: Modeling and optimization using response surface methodology
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Production of microporous palm shell based activated carbon for methane adsorption: Modeling and optimization using response surface methodology
چکیده انگلیسی

In this study, the optimization of the palm shell based activated carbon production using combination of chemical and physical activation for methane adsorption is investigated. response surface methodology (RSM) in combination with central composite design (CCD) was used to optimize the operating parameters of the production process. Physical activation temperature, chemical impregnation ratio and physical activation time were chosen as the main process variables and the amount of methane adsorption was selected as the investigated response. Phosphoric acid and carbon dioxide were used as chemical and physical agents, respectively. The optimum reaction conditions were found to be a physical activation temperature of 855 °C, H3PO4 impregnation ratio of 9.42 g of phosphorous per gram palm shell and physical activation time of 135 min. The results exhibited significant increase in methane adsorption after physio-chemical activation.


► The RSM was applied to study the preparation of activated carbon from palm shell.
► More homogenous pore size distribution was achieved by physicochemical activation.
► Overall methane adsorption capacity of the ACs enhanced by this activation method.
► Adsorption of methane not only depends upon the BET surface area.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Research and Design - Volume 90, Issue 6, June 2012, Pages 776–784
نویسندگان
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