کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
62244 | 47629 | 2009 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: In situ preparation of Ni–Cu/TiO2 bimetallic catalysts In situ preparation of Ni–Cu/TiO2 bimetallic catalysts](/preview/png/62244.png)
A nanoscale investigation was performed on the initial stages of the formation of nanoparticles during the preparation of NiCu/TiO2 bimetallic catalysts by incipient wetness impregnation. The evolution of the structure and chemistry of individual nanoparticles was followed in the reaction cell of an environmental transmission electron microscope. During reduction in hydrogen at 300 °C, nuclei quickly formed and grew mainly via Ostwald ripening or short-range particle–particle coalescence. The presence of Cu greatly enhanced the reducibility of the Ni species and about 85% of the particles were metallic. Most of the particles were uniform in composition but approximately 15% of the particles showed Ni enrichment on the surface. The surface enrichment of Ni was attributed to differential diffusion processes and demonstrated that, for the reduction temperature used for this experiment, the structure of the bimetallic particles was controlled by kinetics rather than by thermodynamics.
A nanoscale view of the processes that may occur when co-impregnation techniques are employed in the preparation of bimetallic catalysts. Salt solution interacts with support and thermal processing results in decomposition of precursor. Reduction leads to nucleation and growth of bimetallic particles which may vary in composition.Figure optionsDownload high-quality image (78 K)Download as PowerPoint slide
Journal: Journal of Catalysis - Volume 262, Issue 1, 15 February 2009, Pages 73–82