کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
622900 1455310 2016 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Physico-chemical local equilibrium influencing cation transport in electrodialysis of multi-ionic solutions
ترجمه فارسی عنوان
تعادل فیزیکی و شیمیایی محلی بر روی انتقال کاتیون در الکترو دی دیالیز راه حل های چند یونی تاثیر می گذارد
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی


• Electrodialytic removal of solutions containing ternary mixture of electrolytes
• Physico-chemical local equilibriums during cation transport
• Theoretically estimated LCD could closely (± 5–7%) predict experimental data.
• Cations with higher charge had low transport number, high adsorption and resistance.

Electrodialysis (ED) of solutions containing ternary combination of electrolytes (NaCl, KCl, CaCl2, MgCl2, FeCl3) was carried out. Besides linear velocity of the fluid flowing through the ED cell, physical properties of cations and their interaction with the gel phase of membrane significantly influenced ion transport. The role of concentration polarization was evaluated from limiting current density (LCD) measurement. Theoretically estimated LCD values based on effective diffusivity of each ions and mass transfer coefficients (Sherwood number, Sh correlation) satisfactorily (error ± 5–7%) predicted experimental data. Measurement of transport number, adsorption equilibrium, water uptake and membrane resistance were carried out for each composition to understand the role of cations — membrane equilibrium in ion transport. Cations with higher charges showed reduced transport number, higher adsorption and higher resistance over cation exchange membrane (CEM). Water uptake measurement of equilibrated CEM showed negligible difference when cations of similar charges were interchanged while a meager 1.5% variation was noted when cations of different charges were interchanged.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 385, 2 May 2016, Pages 93–105
نویسندگان
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