کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
62304 47632 2010 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Carbon nanofibre-supported palladium catalysts as model hydrodechlorination catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Carbon nanofibre-supported palladium catalysts as model hydrodechlorination catalysts
چکیده انگلیسی

Different carbon nanofibre-supported palladium catalysts (Pd/CNF) were prepared and tested for tetrachloroethylene hydrodechlorination. Catalyst properties were varied by changing metal loading (0.5% and 1% wt.), preparation procedure (aqueous or organic solutions), and support chemistry (parent or HNO3-oxidised CNFs). Fresh and used (during 108,000 s at 0.5 MPa, 523 K, 24 g s mmol−1 space time) catalysts were characterised by TEM, XRD, TPD, TPO–MS, nitrogen physisorption, and XPS. Results obtained indicate that the preparation method (using aqueous or organic precursor) plays a key role both in the intrinsic activity of the catalysts (higher for aqueous solutions), and catalyst deactivation (also faster for aqueous solutions).The surface chemistry of the support, influenced by the surface activation and the preparation procedure, markedly affects the Pd2+/Pd0 ratio (found to be optimal at about 0.3–0.6) and chlorine concentration, these parameters determining the catalysts performance. In general terms, aqueous precursors lead to the highest initial activity (maximum initial TOF of 18 s−1, whereas the maximum initial TOF for catalysts prepared from organic precursor is of 5.6 s−1) and faster deactivation (minimum TOF108,000s/TOF0 of 0.06 and 0.38, respectively). Deactivation causes were observed to be different in both cases: coke formation for the aqueous precursor and chlorine poisoning for the organic-phase precursor.

The activity and deactivation of different CNF-supported palladium catalysts (using different precursors and surface treatments) for tetrachloroethylene hydrodechlorination have been studied in this work. It was observed that the behaviour of the catalysts changes markedly with the treatment of the surface and, more markedly, with the impregnation procedure (using organic or aqueous solutions). Characterisation of the fresh and aged samples by different techniques allows to explain this behaviour.Figure optionsDownload high-quality image (78 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 272, Issue 1, 25 May 2010, Pages 158–168
نویسندگان
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