Ammonium removal from aqueous solution by zeolites synthesized from low-calcium and high-calcium fly ashes

In this study, zeolites are synthesized from low-calcium (LC-Z) and high-calcium (HC-Z) fly ashes, respectively. The changes of mineralogy, morphology, cation exchange capacity (CEC) and specific surface area (SSA) are investigated during the synthesis process. The equilibrium uptake of ammonium on the two synthesized zeolites is compared. The main crystals of LC-Z and HC-Z are identified as faujasite and gismondine, respectively. The CEC and SSA increase significantly following the conversion process. The kinetic studies showed that the adsorption process of ammonium on both LC-Z and HC-Z follows Ho's pseudo-second-order model. Langmuir model agrees better with the equilibrium data for LC-Z, while Freundlich model gives the better fit for HC-Z. The obtained maximum ammonium uptake capacities are 23.8 mg/g for LC-Z and 3.17 mg/g for HC-Z in the synthetic solution. LC-Z also exhibits much better performance in ammonium uptake in effluent from a sewage treatment plant than HC-Z. These results indicate that LC-Z is a promising material for ammonium removal whereas HC-Z is not. The Ca2+ leaching and the lower zeolite content in HC-Z account for its lower uptake capacity. Thus, the low-calcium fly ash should be chosen preferentially as the raw material of the zeolite synthesis for ammonium removal.

XRD patterns of synthesized zeolites from low-calcium (LC-Z) and high-calcium (HC-Z) fly ashes.Figure optionsDownload as PowerPoint slideResearch highlights
► Low-calcium and high-calcium fly ashes were turned into zeolites (LC-Z and HC-Z).
► LC-Z has a higher ammonium removal capacity than HC-Z.
► Ca2+ leaching and lower zeolite content in HC-Z account for its lower uptake capacity.
► The zeolite should be synthesized from low-calcium fly ash for ammonium removal.