کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
625399 | 1455428 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermodynamic and kinetic investigations of phosphate adsorption onto hydrous niobium oxide prepared by homogeneous solution method
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The adsorption kinetics of phosphate onto Nb2O5·nH2O was investigated at initial phosphate concentrations 10 and 50 mg Lâ1. The kinetic process was described by a pseudo second-order rate model very well. The adsorption thermodynamics was carried out at 298, 308, 318, 328 and 338 K. The positive values of both ÎH and ÎS suggest an endothermic reaction and increase in randomness at the solid-liquid interface during the adsorption. ÎG values obtained were negative indicating a spontaneous adsorption process. The Langmuir model described the data better than the Freundlich isotherm model. The peak appearing at 1050 cmâ1 in IR spectra after adsorption was attributed to the bending vibration of adsorbed phosphate. The effective desorption could be achieved using water at pH 12.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 263, Issues 1â3, 30 November 2010, Pages 29-35
Journal: Desalination - Volume 263, Issues 1â3, 30 November 2010, Pages 29-35
نویسندگان
Liana Alvares Rodrigues, Maria Lúcia Caetano Pinto da Silva,