کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
625556 1455429 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study on the photocatalytic degradation of insecticide methomyl in water
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Study on the photocatalytic degradation of insecticide methomyl in water
چکیده انگلیسی

Photo-Fenton degradation of the insecticide methomyl in water using Fe-ZSM-5 zeolite and AlFe-pillared montmorillonite catalysts under halogen lamp light was studied. The study was performed at room temperature in a glass batch reactor under constant airflow. Both catalysts exhibited activity in the wet oxidative degradation of methomyl. The rate of photodecomposition of methomyl was measured using UV spectrometry and HPLC, while its mineralization was followed using ion chromatography (IC) and total organic carbon (TOC) analyzer. IC results showed that mineralization led to formation of sulfate, nitrate and ammonium ions during the process. Under our conditions, complete disappearance of 16.22 mg/L of pure pesticide and 100% or 80% TOC removal occurred within 4 h using 5 g/L or 1 g/L of Fe-ZSM-5 zeolite, respectively. The Fe-ZSM-5 was found to be a better catalyst. Pseudo-first-order rate constants were calculated, and the performed treatments compared.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 262, Issues 1–3, 15 November 2010, Pages 228–234
نویسندگان
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