کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
62785 47655 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Direct catalytic asymmetric aldol reactions on chiral catalysts assembled in the interface of emulsion droplets
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Direct catalytic asymmetric aldol reactions on chiral catalysts assembled in the interface of emulsion droplets
چکیده انگلیسی

An amphiphilic proline-based organocatalyst was assembled on the interface of water and oil, resulting in a W/O emulsion. The chiral catalyst in emulsion significantly enhances the reactivity and stereoselectivity of the direct asymmetric aldol reactions, which can be attributed mainly to the larger interfacial surface area and uniformly distributed catalyst molecules in the interface of the emulsion droplets.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 250, Issue 2, 10 September 2007, Pages 360–364
نویسندگان
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