کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
629040 1455498 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation of poly(vinylidene fluoride) (PVDF) membranes via thermally induced phase separation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Formation of poly(vinylidene fluoride) (PVDF) membranes via thermally induced phase separation
چکیده انگلیسی

The effects of diluents, thermodynamic interactions, different quenching conditions and coarsening on the morphology of poly(vinylidene fluoride) (PVDF) membranes via thermally induced phase separation were investigated. Scanning electron microscopy indicated that an interconnected spherulitic structure was obtained in the PVDF–DMP system, while the PVDF–DMP–DOS and PVDF–DMP–DOA systems showed a jagged and sharp-edged spherulitic structure. As the interactions decreased, the spherulitic structure was increasingly non-discernable and the value of porosity increased in the order of PVDF–DMP, PVDF–DMP–DOA, PVDF–DBP and PVDF–DMP–DOS. When quenching in 353 K and 368 K, the spherulities became more discernable, and the size of spherulity increased. When quenching in different conditions, the discernible spherulitic structure was obtained in ice water, a greater spherulitic size was obtained in a water bath at 303 K, and PVDF crystallized much slower and improved in an air bath.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 192, Issues 1–3, 10 May 2006, Pages 160-167