کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
62932 | 47663 | 2008 | 8 صفحه PDF | دانلود رایگان |
The adsorption and oxidation of ortho-dichlorobenzene (o-DCB) over sulfated zirconia (SZ), Co–SZ, and Pd/Co–SZ were studied by means of in situ FTIR spectroscopy to determine the nature of surface intermediates formed on these catalysts. The results indicate that o-DCB adsorbs on Lewis acid sites, forming surface intermediates that are strongly held on the surface. These intermediates can be subsequently oxidized to yield various partial oxidation products in either the presence or absence of gas-phase oxygen, confirming that surface oxygen is involved in the oxidation process. On Pd/Co–SZ samples, the oxidation is faster in the presence of gas-phase oxygen, yielding higher concentrations of partial oxidation products on the catalyst surface.
Journal: Journal of Catalysis - Volume 258, Issue 1, 15 August 2008, Pages 95–102