کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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63114 | 47671 | 2006 | 11 صفحه PDF | دانلود رایگان |
Four W–Ni catalysts, containing Al2O3, chemically treated zeolite Y, hydrothermally treated zeolite beta, and the combination of the above zeolite Y and beta, were prepared. The catalysts were characterized by BET, NH3-TPD, XRD, TEM, pyridine-IR, and XPS. The reaction performance in hydrodesulfurization (HDS), hydrodenitrogenation (HDN), and hydrodearomatation (HDA) was evaluated with light cycle oil (LCO). The zeolite-containing catalysts exhibited much higher HDN, HDS, and HDA activities than the WNi/Al2O3. The three zeolite-containing catalysts had similar HDN activity. The WNi/Beta + Y and WNi/Beta catalysts had higher HDS activity than the WNi/Y catalyst. The higher HDN, HDS, and HDA activities of the three zeolite-containing catalysts are associated primarily with enhanced hydrogenation activity and increased acidity.
Journal: Journal of Catalysis - Volume 241, Issue 2, 25 July 2006, Pages 435–445