کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6311935 1618932 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Biotransformation of tetrabromobisphenol A (TBBPA) in anaerobic digester sludge, soils, and freshwater sediments
موضوعات مرتبط
علوم زیستی و بیوفناوری علوم محیط زیست شیمی زیست محیطی
پیش نمایش صفحه اول مقاله
Biotransformation of tetrabromobisphenol A (TBBPA) in anaerobic digester sludge, soils, and freshwater sediments
چکیده انگلیسی
The biotransformation of tetrabromobisphenol A (TBBPA) was evaluated in anaerobic digester sludge, soils, and freshwater sediments. In anaerobic digester sludge, TBBPA biotransformed rapidly with a 50% disappearance time (DT50) of 19 days, though little mineralization (1.1%) was observed. In aerobic soils, mineralization of TBBPA ranged from 17.5% to 21.6% with 55.3-83.6% of the TBBPA incorporated into the soils as a non-extractable bound residue. The DT50 for TBBPA in aerobic soils ranged from 5.3 to 7.7 days. In anaerobic soils, 48.3-100% of the TBBPA was incorporated into the soils as non-extractable bound residue with <4% mineralized. The soil fate studies demonstrated extensive incorporation of TBBPA into the solid matrix and this association was related to the amount of organic carbon in the soils (i.e., greater association of TBBPA with soil at higher organic carbon content). In anaerobic sediments the DT50 for TBBPA ranged from 28 to 42 days, whereas in aerobic sediments the DT50 for TBBPA ranged from 48 to 84 days and depended on the initial dose concentration. Most of the TBBPA in the sediment studies was incorporated as a non-extractable bound residue with little mineralization observed. Sediment extracts revealed three unknown biotransformation products and bisphenol A (BPA). These results were consistent with previously published studies where TBBPA biotransformed in anaerobic environments (digester sludge and sediments) by debromination and slowly mineralized in the test environments (anaerobic digester sludge, soils, and freshwater sediments).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ecotoxicology and Environmental Safety - Volume 131, September 2016, Pages 143-150
نویسندگان
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