کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
632158 1455979 2016 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sorption and transport of CO2 in copolymers containing soft (PEO, PPO) and hard (BKDA-ODA and BPDA-ODA) segments at different temperatures: Experimental data and modeling
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Sorption and transport of CO2 in copolymers containing soft (PEO, PPO) and hard (BKDA-ODA and BPDA-ODA) segments at different temperatures: Experimental data and modeling
چکیده انگلیسی
In particular, by studying the shape of the solubility isotherm, as well as the values of diffusivity, sorption enthalpy and activation energy, we were able to monitor the transition from a glassy-like to a rubbery-like behavior as the fraction of rubbery component in the copolymer increases. The data indicate that polyether enhances CO2 permeability by acting mostly on diffusivity, while the solubility contribution is less affected on a quantitative basis. However, the qualitative behavior of solubility allows understanding the nature of interactions between the two phases. In particular, by using a simple additive approach to estimate the CO2 solubility of the copolymer, and the Non-Equilibrium Lattice Fluid (NELF) to evaluate the CO2 solubility in the pure homopolymers, one concludes that the copolymers sorption behavior is “ideal”, i.e. purely additive, indicating a good combination of the two phases. The copolymer volume, on the other hand, shows a contraction upon combination of the two phases. The NELF modeling of solubility data allows attributing such a contraction only to the glassy phase, whose excess free volume is reduced in the presence of the rubbery portion in the copolymer, which possibly partly occupies such excess volume, indicating a strong interpenetration of the two phases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 520, 15 December 2016, Pages 187-200
نویسندگان
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